Abstract Details
486 / 2019-03-18 17:01:01
High-Pressure Synthesis and Characterization of CeOCl
CeOCl,High-pressure solid-state metathesis reaction,Photoluminescence,Bulk modulus,First-principles calculations
Abstract Accepted
The well-crystallized CeOCl was synthesized by a high-pressure solid-state metathesis (HPSSM) reaction at 5 GPa and 1873 K. The chemical reaction equation can be depicted as: CeCl3 + MgO = CeOCl + MgCl2.
The CeOCl were probed by powder XRD, FE-SEM, EDS, HRTEM, PL and Raman spectroscopy, in situ high-pressure angle-dispersive X-ray diffraction (ADXRD), as well as the first-principles calculations.
Our results showed that CeOCl, with ~3.05 eV band gap, is an indirect (direct) band gap semiconductor for the spin-up (spin-down) branch. In addition, the bulk modulus of CeOCl is determined to be 52.8(8) GPa, which is close to our first-principles calculations, giving that B0 = 47.6(5) GPa.
The CeOCl were probed by powder XRD, FE-SEM, EDS, HRTEM, PL and Raman spectroscopy, in situ high-pressure angle-dispersive X-ray diffraction (ADXRD), as well as the first-principles calculations.
Our results showed that CeOCl, with ~3.05 eV band gap, is an indirect (direct) band gap semiconductor for the spin-up (spin-down) branch. In addition, the bulk modulus of CeOCl is determined to be 52.8(8) GPa, which is close to our first-principles calculations, giving that B0 = 47.6(5) GPa.
Important Date
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Conference Date
May 29
2019
toJun 02
2019
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Mar 20 2019
Abstract Submission Deadline
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Mar 20 2019
Draft paper submission deadline
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Apr 10 2019
Abstract Notification of Acceptance
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Jun 02 2019
Registration deadline
Organized By
Institute of Applied Physics and Computational Mathematics
Laser Fusion Research Center, China Academy of Engineering Physics
Xi'an Jiaotong University
Laser Fusion Research Center, China Academy of Engineering Physics
Xi'an Jiaotong University
Contact Information
- Prof. Hongliang He
- mr******@caep.cn
Previous Conferences
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2026-05-12 China Xiamen
The 9th International Conference on Matter and Radiation at Extremes (ICMRE2026) -
2025-05-12 China 西安市
The 8th International Conference on Matter and Radiation at Extremes -
2024-05-13 China Hangzhou
7th International Conference on Matter and Radiation at Extremes -
2023-06-05 China Zhuhai
The 6th International Conference on Matter and Radiation at Extremes -
2020-05-25 China Xi'an
The 5th International Conference on Matter and Radiation at Extremes -
2017-06-01 China Beijing,China
2nd International Conference on Matter and Radiation at Extremes
