24th International Conference on Phosphorus Chemistry (ICPC24)

71 / 2023-08-22 12:44:39

Diphosphino-Substituted Diazomethane Transition Metal Complexes

N-Heterocyclic Phosphino (NHP),Carbene

Phosphorus in Synthetic Chemistry > 2) Phosphorus compounds as ligands

Abstract The N-Heterocyclic Phosphino (NHP) serves as a type of π-electron donating substituent. In the realm of low-valent main group chemistry, it finds utility in stabilizing singlet phosphinidene,^[1] monometal-substituted free carbenes,^[2] copper carbyne anion complexes,^[3] and ketenyl anions.^[4] As a result, it exhibits promising applications in the study of novel stable low-valent main group compounds. In this study, we employed the NHP substituent to synthesize (bisphosphino)diazomethane and investigated its coordination reactions with transition metals, leading to the synthesis of a novel bisphosphino transition metal carbene complex. This complex was characterized using nuclear magnetic resonance (NMR), high-resolution mass spectrometry (HRMS), and crystallography.







Fig. 1 Sturcture of the N-Heterocyclic Phosphino (NHP)



Keywords：N-Heterocyclic Phosphino (NHP); Carbene





Reference

[1] Liu, L. L.; Ruiz, D. A.; Munz, D.; Bertrand, G., Chem 2016, 1, 147-153.

[2] Hu, C. Y.; Wang, X. -F.; Wei, R.; Hu, C. P.; Ruiz, D. A.; Chang, X. Y.; Liu, L. L., Chem 2022, 8, 2278-2289.

[3] Wei, R.; Wang, X.-F.; Hu, C.; Liu, L. L., Nat. Synth. 2023, 2, 357-363.

[4] Wei, R.; Wang, X. -F.; Ruiz, D. A.; Liu, L. L., Angew. Chem. Int. Ed. 2023, 62, e202219211.