第十五届全国摩擦学大会暨全国青年摩擦学学术会议

803 / 2022-07-04 15:50:24

空气污染物对范德华接触界面摩擦性质的影响

The distribution of nanoparticles (NPs) on graphene is crucial for the performance of the graphene-based device. Such distribution would be obviously influenced by the supporting substrates of graphene which are essential for the device.However, there are only few relevant studies. In this paper, we report the distinct difference in the distributions of sulfur clusters at the sub-micron scale on the suspended graphene compared to a supported one. With vapor deposition of sulfur onto graphene with a patterned substrate, we find that the density of sulfur clusters on the supported regions is 3 to 8 times larger than that on the suspended ones. While the density decreases as the number of graphene layers increases for the supported regions, the opposite trend is observed within the suspended ones. The density also increases with the area of the suspended regions. The mechanism underlying these phenomena is attributed to the diffusion of small sulfur NPs which coalesce into larger sulfur clusters at the sub-micron scale on graphene, with faster diffusion on the suspended regions due to the more pronounced ripples in suspended graphene. Our results highlight the importance of the supporting substrates and provide guidelines for the fabrication of the graphene-based device.